Source: SEACOAST SCIENCE, INC. submitted to
AN INEXPENSIVE MEMS-BASED PESTICIDE DETECTOR FOR LONG-TERM MONITORING
Sponsoring Institution
National Institute of Food and Agriculture
Project Status
TERMINATED
Funding Source
Reporting Frequency
Annual
Accession No.
0206567
Grant No.
2006-33610-16764
Project No.
CALK-2006-00188
Proposal No.
2006-00188
Multistate No.
(N/A)
Program Code
8.4
Project Start Date
May 1, 2006
Project End Date
Jun 30, 2007
Grant Year
2006
Project Director
Mlsna, T. E.
Recipient Organization
SEACOAST SCIENCE, INC.
2151 LAS PALMAS DRIVE, SUITE C
CARLSBAD,CA 92011
Performing Department
(N/A)
Non Technical Summary
Pesticides are a continuing source and significant contributor to decreases in air quality. Most pesticides create risk to humans, animals, or the environment by causing health problems, such as birth defects, nerve damage, cancer, and effects that might manifest themselves in the future. Accurate tracking of residual pesticides can aid in eliminating these effects. Today, accurate monitoring requires that samples be collected in the field and transported to a laboratory for analysis; a costly and time-consuming method. To aid in the safe usage and monitoring of pesticides, Seacoast Science, proposes to develop an inexpensive, portable sensor system capable of accurately detecting pesticides and their degradation products. Seacoast Science will design an inexpensive Handheld Pesticide Detector (HPD) for industrial and regulatory use. This microelectromechanical systems (MEMS) sensor system utilizes an array of micromachined capacitors, each coated with chemoselective polymers optimized for detecting and identifying pesticides. Capable of detecting volatile components of many pesticide mixtures, each device has ten sensors on a single chip, with several different coatings for redundancy and interferent rejection. The MEMS transducers require little power and are inexpensive to produce in large quantities. Long-term, unattended monitoring of storage and manufacturing sites may be possible for the first time.
Animal Health Component
(N/A)
Research Effort Categories
Basic
(N/A)
Applied
100%
Developmental
(N/A)
Classification

Knowledge Area (KA)Subject of Investigation (SOI)Field of Science (FOS)Percent
1330410200050%
1330410202050%
Knowledge Area
133 - Pollution Prevention and Mitigation;

Subject Of Investigation
0410 - Air;

Field Of Science
2020 - Engineering; 2000 - Chemistry;
Goals / Objectives
The overall objective of this program is to demonstrate the feasibility of an inexpensive, low-power, lightweight pesticide detector using multiple MEMS-based micro capacitor sensors. The initial objective of the Phase I program is to demonstrate detection of the chemicals of interest and establish lower limits of detection without preconcentration. This information will then be used to design a detector system that could be built in Phase I, and contains a sampling system with preconcentration, a sensor array, and which outputs data identifying and quantifying chemicals of interest. Our specific design will have the following features: 1.An array of microcapacitor sensors coated with Seacoast Science's chemoselective polymers. 2.Signal processing and communication circuits that are currently being commercialized by Seacoast Science for the MEMS detector. 3.A detector unit target cost of under $250 in volumes of over 10,000
Project Methods
We will begin with characterization and optimization of our current sensor array for detection of the three sample fumigants: dichloropropene, methyl bromide, and methyl isothiocyanate. These materials represent some of the commonly used fumigants, herbicides or insecticides and are ranked in the top 15 by both the EPA and the Cal. Dept of Pesticide Regulation. This will be followed by an optimized design of the Seacoast Science microcapacitor sensor system for the detection of those chemicals over the desired range of concentrations. The work done will be summarized in monthly reports. The specific Phase I objectives are: 1. Optimize the chemoselective polymer coatings applied to the microcapacitor sensors for the detection of chosen fumigants. 2. Characterize the Phase I prototype using pesticides and interferents. 3. Characterize the requirements of a sampling/preconcentration system. 4. Complete and document the design of an inexpensive mass-producible pesticide detector system that will meet detection requirements after further development in Phase II

Progress 05/01/06 to 06/30/07

Outputs
This Phase I SBIR project concerned the research and development towards the design of an inexpensive Handheld Pesticide Detector (HPD) for industrial and regulatory use. This microelectromechanical systems (MEMS) sensor system uses an array of micromachined capacitors coated with chemoselective materials optimized for detecting and identifying pesticides. Capable of detecting volatile components of many pesticide mixtures, each device has ten sensors on a single chip, with several different coatings for redundancy and interferrent rejection. The MEMS transducers require little power and are inexpensive to produce in large quantities. Long-term, unattended monitoring of storage and manufacturing sites may be possible for the first time. Research Carried Out. Objective #1: Optimized the chemoselective materials: Initial polymer arrays were prepared from 8 different commercial and newly synthesized proprietary materials. A total of thirty-four materials from 5 different classes were prepared and analyzed against the target pesticides. Objective #2: Tested Pesticides and Interferrents: Sensor arrays were tested against the three target pesticides and potential interferrents Objective #3: Characterized the requirements of a sampling/ preconcentration system: Objective #4: Completed and documented the design of an inexpensive mass-producible pesticide detector system. Research Results. This Phase I SBIR project met or exceeded the goals established in the proposal. Thirty-four materials were prepared from the classes of transition metal nanoparticles, functionalized polysiloxanes, functionalized hyperbranched polycarbosilanes, organic bridged polysilsesquioxanes, and amine doped bridged polysilsesquioxanes. These materials were synthesized, characterized and tested against the target high vapor pressure pesticides and against interferrents. The limits of detection obtained during this Phase I project compare favorably with the toxicity of these pesticides Potential Applications. Applications for the technology developed in this program include pesticide storage monitoring, industrial leak detection, regulatory inspections, and point-of-use monitoring. Industrial facilities can use these systems as handheld detectors for cleanup crews and first responders, or when networked as long-term leak detectors. Regulatory agencies can used these detectors in compliance checks, or to monitor pesticide movement in the air in from farms to less rural areas. In addition, pest control services can use these detectors to determine when buildings are safe for reentry or to monitor exposure by workers. The microcapacitor sensor technology being developed by Seacoast Science, and proposed for use in the Handheld Pesticide Detector (HPD) described in this proposal, has much broader relevance for a number of commercial applications. These sensors are ideal for monitoring a variety of chemical and physical targets in a distributed system where a premium is placed on early detection of problems.

Impacts
This program will have enormous impact in the monitoring of high-volume pesticides. The resulting system will allow the real-time detection of dangerous chemicals an will insure the health and safety of the public. One specific application will be the protection of children at school that are proximate to agricultural site that use such pesticides. The resultant information will allow public health official to assess the dangers from these chemicals and will assuage parents and other concern individuals. The system will also benefit the farmers by allowing them to use the minimum amount of compounds by allowing them to precisely measure its concentration. Finally, the surveillance of these compounds will allow environmental managers to probe the effects of these pesticides on native flora and fauna.

Publications

  • No publications reported this period